Unlocking the Future of Microelectronics With Argonne’s Redox Gating Breakthrough

Illustration of redox gating for carrier manipulation and electric field control of the electronic state. The green threads represent functional molecules for redox gating, and the ability to function at low power mimics synaptic switching in the human brain, as represented by the underlying synapse. Credit: Argonne National Laboratory

Argonne researchers pioneer “redox gating” — a new way to precisely modulate electron flow.

Breakthrough could help lead to the development of new low-power <span class="glossaryLink" aria-describedby="tt" data-cmtooltip="

semiconductors

Semiconductors are a type of material that has electrical conductivity between that of a conductor (such as copper) and an insulator (such as rubber). Semiconductors are used in a wide range of electronic devices, including transistors, diodes, solar cells, and integrated circuits. The electrical conductivity of a semiconductor can be controlled by adding impurities to the material through a process called doping. Silicon is the most widely used material for semiconductor devices, but other materials such as gallium arsenide and indium phosphide are also used in certain applications.

” data-gt-translate-attributes=”[{"attribute":"data-cmtooltip", "format":"html"}]” tabindex=”0″ role=”link”>semiconductors or quantum devices.

As the integrated circuits that power our electronic devices get more powerful, they are also getting smaller. This trend of microelectronics has only accelerated in recent years as scientists try to fit increasingly more semiconducting components on a chip.

Overcoming the Heat Challenge

Microelectronics face a key challenge because of their small size. To avoid overheating, microelectronics need to consume only a fraction of the electricity of conventional electronics while still operating at peak performance.

Breakthrough in Material Science

Researchers at the U.S. Department of Energy’s (DOE) Argonne National Laboratory have achieved a breakthrough that could allow for a new kind of microelectronic material to do just that. In a new study published in Advanced Materials, the Argonne team proposed a new kind of “redox gating” technique that can control the movement of electrons in and out of a semiconducting material.

“The subvolt regime, which is where this material operates, is of enormous interest to researchers looking to make circuits that act similarly to the human brain, which also operates with great energy efficiency.”

— Argonne materials scientist Wei Chen

Understanding “Redox Gating”

“Redox” refers to a chemical reaction that causes a transfer of electrons. Microelectronic devices typically rely on an electric “field effect” to control the flow of electrons to operate. In the experiment, the scientists designed a device that could regulate the flow of electrons from one end to another by applying a voltage — essentially, a kind of pressure that pushes electricity — across a material that acted as a kind of electron gate. When the voltage reached a certain threshold, roughly half of a volt, the material would begin to inject electrons through the gate from a source redox material into a channel material.

By using the voltage to modify the flow of electrons, the semiconducting device could act like a transistor, switching between more conducting and more insulating states.

Advantages of the New Technique

“The new redox gating strategy allows us to modulate the electron flow by an enormous amount even at low voltages, offering much greater power efficiency,” said Argonne materials scientist Dillon Fong, an author of the study. “This also prevents damage to the system. We see that these materials can be cycled repeatedly with almost no degradation in performance.”

“Controlling the electronic properties of a material also has significant advantages for scientists seeking emergent properties beyond conventional devices,” said Argonne materials scientist Wei Chen, one of the study’s co-corresponding authors.

“The subvolt regime, which is where this material operates, is of enormous interest to researchers looking to make circuits that act similarly to the human brain, which also operates with great energy efficiency,” he said.

Implications for Future Technologies

The redox gating phenomenon could also be useful for creating new quantum materials whose phases could be manipulated at low power, said Argonne physicist Hua Zhou, another co-corresponding author of the study. Moreover, the redox gating technique may extend across versatile functional semiconductors and low-dimensional quantum materials composed of sustainable elements.

Reference: “Redox Gating for Colossal Carrier Modulation and Unique Phase Control” by Le Zhang, Changjiang Liu, Hui Cao, Andrew J. Erwin, Dillon D. Fong, Anand Bhattacharya, Luping Yu, Liliana Stan, Chongwen Zou, Matthew V. Tirrell, Hua Zhou and Wei Chen, 6 January 2024, Advanced Materials.
DOI: 10.1002/adma.202308871

Work done at Argonne’s Advanced Photon Source, a DOE Office of Science user facility, helped characterize the redox gating behavior.

Additionally, Argonne’s Center for Nanoscale Materials, also a DOE Office of Science user facility, was used for materials synthesis, device fabrication and electrical measurements of the device.

A paper based on the study, “Redox Gating for Colossal Carrier Modulation and Unique Phase Control,” appeared in the January 6, 2024 issue of Advanced Materials. In addition to Fong, Chen and Zhou, contributor authors include Le Zhang, Changjiang Liu, Hui Cao, Andrew Erwin, Dillon Fong, Anand Bhattacharya, Luping Yu, Liliana Stan, Chongwen Zou and Matthew V. Tirrell.

The work was funded by DOE’s Office of Science, Office of Basic Energy Sciences, and Argonne’s laboratory-directed research and development program.